Crystal and molecular structure of the ethanol adduct of tris(oxinato)indium(III)
Identifieur interne : 000202 ( Main/Exploration ); précédent : 000201; suivant : 000203Crystal and molecular structure of the ethanol adduct of tris(oxinato)indium(III)
Auteurs : RBID : ISTEX:10870_1994_Article_BF01668231.pdfEnglish descriptors
- KwdEn :
Abstract
The ethanol adduct of tris(oxinato)indium(III), prepared in aqueous ethanol, crystallizes in the monoclinic space groupP21/n (Nr.14) witha=11.343(2),b=13.477(3),c=16.845(2)Å, β-94.71(1)°,V=2566.4(8)Å3 andZ=4. The structure was solved by direct methods and refined by full-matrix least-squares methods toR=0.032 for 3374 observed reflections withI>2 σ(I). Three bidentate oxinato ligands (or 8-quinolinolato) coordinate to indium atom leading to an approximately octahedral coordination of the metal(III) ion. One ethanol molecule per mole of metal complex is occluded in the crystal lattice and forms a hydrogen bond with the O(3) oxygen atom of one oxinato ligand [O(3) ... O(4) =2.715(3) Å]. The two other oxinato ligands of the same unit are not involved in hydrogen bonding.
DOI: 10.1007/BF01668231
Links toward previous steps (curation, corpus...)
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title>Crystal and molecular structure of the ethanol adduct of tris(oxinato)indium(III)</title><author><name>N. Korber</name><affiliation wicri:level="1"><mods:affiliation>Max-Planck-Institut für Festkörperforschung, Heisenbergstr. 1, D-70506, Stuttgart, Germany</mods:affiliation><country xml:lang="fr">Allemagne</country><wicri:regionArea>Max-Planck-Institut für Festkörperforschung, Heisenbergstr. 1, D-70506, Stuttgart</wicri:regionArea><wicri:noRegion>70506, Stuttgart</wicri:noRegion><wicri:noRegion>Stuttgart</wicri:noRegion></affiliation></author><author><name>B. Achour</name><affiliation wicri:level="3"><mods:affiliation>Laboratoire de Ciblage en Thérapeutique, Université Paul Sabatier, 35, Ch. des Maraichers, F-31062, Toulouse Cedex, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Ciblage en Thérapeutique, Université Paul Sabatier, 35, Ch. des Maraichers, F-31062, Toulouse Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Midi-Pyrénées</region><settlement type="city">Toulouse</settlement></placeName></affiliation></author><author><name>F. Nepveu</name><affiliation wicri:level="3"><mods:affiliation>Laboratoire de Ciblage en Thérapeutique, Université Paul Sabatier, 35, Ch. des Maraichers, F-31062, Toulouse Cedex, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Ciblage en Thérapeutique, Université Paul Sabatier, 35, Ch. des Maraichers, F-31062, Toulouse Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Midi-Pyrénées</region><settlement type="city">Toulouse</settlement></placeName></affiliation></author></titleStmt><publicationStmt><idno type="RBID">ISTEX:10870_1994_Article_BF01668231.pdf</idno><date when="1994">1994</date><idno type="doi">10.1007/BF01668231</idno><idno type="wicri:Area/Main/Corpus">000004</idno><idno type="wicri:Area/Main/Curation">000004</idno><idno type="wicri:Area/Main/Exploration">000202</idno></publicationStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>8-hydroxyquinoline</term><term>8-quinolinol</term><term>Indium</term><term>Molecular structure</term><term>Oxine</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="eng">The ethanol adduct of tris(oxinato)indium(III), prepared in aqueous ethanol, crystallizes in the monoclinic space groupP21/n (Nr.14) witha=11.343(2),b=13.477(3),c=16.845(2)Å, β-94.71(1)°,V=2566.4(8)Å3 andZ=4. The structure was solved by direct methods and refined by full-matrix least-squares methods toR=0.032 for 3374 observed reflections withI>2 σ(I). Three bidentate oxinato ligands (or 8-quinolinolato) coordinate to indium atom leading to an approximately octahedral coordination of the metal(III) ion. One ethanol molecule per mole of metal complex is occluded in the crystal lattice and forms a hydrogen bond with the O(3) oxygen atom of one oxinato ligand [O(3) ... O(4) =2.715(3) Å]. The two other oxinato ligands of the same unit are not involved in hydrogen bonding.</div></front></TEI><mods xsi:schemaLocation="http://www.loc.gov/mods/v3 file:///applis/istex/home/loadistex/home/etc/xsd/mods.xsd" version="3.4" istexId="014f9c8c3f8490a24ef8186a837d0a7bd1497c9a"><titleInfo lang="eng"><title>Crystal and molecular structure of the ethanol adduct of tris(oxinato)indium(III)</title></titleInfo><name type="personal"><namePart type="given">N.</namePart><namePart type="family">Korber</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Max-Planck-Institut für Festkörperforschung, Heisenbergstr. 1, D-70506, Stuttgart, Germany</affiliation></name><name type="personal"><namePart type="given">B.</namePart><namePart type="family">Achour</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Laboratoire de Ciblage en Thérapeutique, Université Paul Sabatier, 35, Ch. des Maraichers, F-31062, Toulouse Cedex, France</affiliation></name><name type="personal"><namePart type="given">F.</namePart><namePart type="family">Nepveu</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Laboratoire de Ciblage en Thérapeutique, Université Paul Sabatier, 35, Ch. des Maraichers, F-31062, Toulouse Cedex, France</affiliation></name><typeOfResource>text</typeOfResource><genre>Original Paper</genre><originInfo><publisher>Kluwer Academic Publishers-Plenum Publishers, New York</publisher><dateCreated encoding="w3cdtf">1994-02-17</dateCreated><dateCaptured encoding="w3cdtf">1994-06-08</dateCaptured><dateValid encoding="w3cdtf">2005-04-26</dateValid><copyrightDate encoding="w3cdtf">1994</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="eng">The ethanol adduct of tris(oxinato)indium(III), prepared in aqueous ethanol, crystallizes in the monoclinic space groupP21/n (Nr.14) witha=11.343(2),b=13.477(3),c=16.845(2)Å, β-94.71(1)°,V=2566.4(8)Å3 andZ=4. The structure was solved by direct methods and refined by full-matrix least-squares methods toR=0.032 for 3374 observed reflections withI>2 σ(I). Three bidentate oxinato ligands (or 8-quinolinolato) coordinate to indium atom leading to an approximately octahedral coordination of the metal(III) ion. One ethanol molecule per mole of metal complex is occluded in the crystal lattice and forms a hydrogen bond with the O(3) oxygen atom of one oxinato ligand [O(3) ... O(4) =2.715(3) Å]. The two other oxinato ligands of the same unit are not involved in hydrogen bonding.</abstract><subject lang="eng"><genre>Key Words</genre><topic>Indium</topic><topic>8-hydroxyquinoline</topic><topic>oxine</topic><topic>8-quinolinol</topic><topic>molecular structure</topic></subject><relatedItem type="series"><titleInfo type="abbreviated"><title>J Chem Crystallogr</title></titleInfo><titleInfo><title>Journal of Chemical Crystallography</title><partNumber>Year: 1994</partNumber><partNumber>Volume: 24</partNumber><partNumber>Number: 10</partNumber></titleInfo><genre>Archive Journal</genre><originInfo><dateIssued encoding="w3cdtf">1994-10-01</dateIssued><copyrightDate encoding="w3cdtf">1994</copyrightDate></originInfo><subject usage="primary"><topic>Chemistry</topic><topic>Inorganic Chemistry</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Crystallography</topic></subject><identifier type="issn">1074-1542</identifier><identifier type="issn">Electronic: 1572-8854</identifier><identifier type="matrixNumber">10870</identifier><identifier type="local">IssueArticleCount: 13</identifier><recordInfo><recordOrigin>Plenum Publishing Corporation, 1994</recordOrigin></recordInfo></relatedItem><identifier type="doi">10.1007/BF01668231</identifier><identifier type="matrixNumber">Art6</identifier><identifier type="local">BF01668231</identifier><accessCondition type="use and reproduction">MetadataGrant: OpenAccess</accessCondition><accessCondition type="use and reproduction">AbstractGrant: OpenAccess</accessCondition><accessCondition type="restriction on access">BodyPDFGrant: Restricted</accessCondition><accessCondition type="restriction on access">BodyHTMLGrant: Restricted</accessCondition><accessCondition type="restriction on access">BibliographyGrant: Restricted</accessCondition><accessCondition type="restriction on access">ESMGrant: Restricted</accessCondition><part><extent unit="pages"><start>685</start><end>688</end></extent></part><recordInfo><recordOrigin>Plenum Publishing Corporation, 1994</recordOrigin><recordIdentifier>10870_1994_Article_BF01668231.pdf</recordIdentifier></recordInfo></mods></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=IndiumV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000202 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000202 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= *** parameter Area/wikiCode missing ***
|area= IndiumV1
|flux= Main
|étape= Exploration
|type= RBID
|clé= ISTEX:10870_1994_Article_BF01668231.pdf
|texte= Crystal and molecular structure of the ethanol adduct of tris(oxinato)indium(III)
}}
| This area was generated with Dilib version V0.5.81. |  |